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Título : Evaluation of N-Alkyl-bis-o-aminobenzamide receptors for the determination and separation of metal ions by fluorescence, UV-visible spectrometry and zeta potential
Otros títulos : Molecules
Autor : Martinez Quiroz, Marisela
Aguilar Martinez, Xiomara E.
Oropeza Guzmán, Mercedes T.
Valdez, Ricardo
López Maldonado, Eduardo A.
Otros Autores: CETYS Universidad
Palabras clave : Zeta potential;Aminobenzamides;;Metal titration;;Fluorescent probes
Sede: Sistemas
Fecha de publicación : 4-may-2019
Citación : 29;9
Resumen : This paper presents the synthesis and evaluation of physicochemical behavior of a new series of N-alkyl-bis-o-aminobenzamides (BOABs) in aqueous solution. The study was targeted to the complexing capacity of five metal ions (Fe2+, Cu2+, Cd2+, Hg2+ and Pb2+) of environmental concern as the medullar principle of a liquid phase sensor for its application in the determination of these metal ions due to its versatility of use. Molecular fluorescence, UV-visible and Zeta potential were measured for five BOABs and the effect of alkyl groups with different central chain length (n = 3, 4, 6, 8 and 10) on physicochemical performance determined. The results have shown that these derivatives present higher sensibility and selectivity for Cu2+ even in the presence of the other metal ions. An additional application test was done adding a pectin (0.1 wt %) solution to the BOAB-Cu+2 complex to obtain a precipitate (flocs) as a potential selective separation process of Cu from aqueous solution. The solid was then lyophilized and analyzed by SEM-EDS, the images showed spheric forms containing Cu+2 with diameter of approximately of 8 μm and 30 wt %.
metadata.dc.description.url: https://www.mdpi.com/1420-3049/24/9/1737
URI : https://repositorio.cetys.mx/handle/60000/582
ISSN : 1420-3049
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